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Chapter 3 of 6

Chemical Bonding and Molecular Structure

Atoms combine with one another through chemical bonds to form more stable arrangements. The two principal types of bonding are ionic and covalent. Ionic bonding occurs when a metal transfers one or more electrons to a nonmetal, creating positively and negatively charged ions, called cations and anions, which are then held together by electrostatic attraction. Covalent bonding, by contrast, involves the sharing of electrons between nonmetal atoms, allowing each atom to achieve a more stable electron configuration.

When two or more atoms join together through covalent bonds, they form a molecule, which represents the smallest unit of a covalent compound. The behavior of atoms in bonding is largely determined by their valence electrons, the electrons in the outermost electron shell. These are the electrons involved in forming chemical bonds, and the number of valence electrons an atom possesses dictates how it interacts with other atoms.

Chemists represent valence electrons visually using Lewis dot structures, which place dots around an atomic symbol to show both bonding and nonbonding, or lone pair, electrons. These diagrams make it possible to predict how atoms will connect, how many bonds a particular atom can form, and what the resulting molecule might look like. Together, ionic and covalent bonding explain the vast diversity of substances found in the natural world.

All chapters
  1. 1Foundations of Matter and Atomic Structure
  2. 2The Periodic Table and Element Classification
  3. 3Chemical Bonding and Molecular Structure
  4. 4Chemical Reactions and Stoichiometry
  5. 5States of Matter, Solutions, and Phase Behavior
  6. 6Acids, Bases, and Chemical Energetics

Drill it

Reading is not remembering. These come from the Chemistry Fundamentals deck:

Q

What is chemistry?

Chemistry is the scientific study of matter, its properties, composition, structure, and the changes it undergoes during chemical reactions.

Q

What is matter?

Matter is anything that has mass and occupies space. It exists in three primary states: solid, liquid, and gas.

Q

What are the three main states of matter?

The three main states of matter are solid (definite shape and volume), liquid (definite volume but indefinite shape), and gas (neither definite shape nor volume...

Q

What is an element?

An element is a pure substance that cannot be broken down into simpler substances by chemical means and is made of only one type of atom.